127v / 220v - One thing that everyone coming to Brazil should be aware of is that there is no national standard voltage for residential buildings in Brazil. Some cities/states have 127v, others have 220v and others still have a mixture of both. One needs to be extremely careful with electical appliances as a result since electrical outlets are almost never marked to indicate the voltage in that circuit. Plugging in a 220v appliance in a 127v circuit is not a big problem, it just won't work. However, plugging a 127v appliance into a 220v outlet could have fatal results. If in doubt always ask somebody before you plug something into an outlet.
There is now a national standard three prong plug and outlet for residential use in Brazil, however this is just recent so you'll find them in only newer buildings. There was no requirement in the law for retrofitting existing buildings with new outlets and as a result there are a great number of very different outlet types in use. While three prong plugs and outlets are now standard, most buildings do not have any ground wires to outlets, construction continues to be two cable wiring service only so don't count on the protection from electric shock that properly grounded outlets provide anywhere in Brazil. Unlike most other nations there is no restriction or special requirements for electrical outlets in bathrooms or other locations where water is also in use such as sinks, washing machines, swimming pools, etc. In North America at least you cannot put an electrical outlet in these locations unless it is the Ground Fault Interrupter (GFI) type. Here in Brazil anything goes so you must be extremely careful.
Showers - most residential construction does not have piped hot water systems so you will most often find electric showers that heat water as it passes through an internal element. In almost every place I've ever been the shower wiring is precarious at best, often completely exposed so extreme caution is necessary to avoid a potentially fatal electric shock. First of all NEVER change the heat setting switch or disconnect the switch without first shutting off the flow of water.Other precautions that should be taken since most of these contraptions are not grounded is to never simply grasp the water shut-off valve, touch it lightly first to make sure you're not going to become part of the circuit of an ungrounded shower. While most of the newer construction uses PVC piping the water itself carries enough of the current from a faulty shower head that touching the valve could give you a serious electric shock. If you in an older building using iron pipes it could be fatal. Always wear flip-flops (called chinelos here) when using this kind of shower. Even though you'll be wet and some current will pass, they could save your life. There's an old wives tale (mostly in the Northeast - Bahia especially) that if you take a shower after a big meal you could die. I'm sure that superstition is the result of people who have actually died of an electrical discharge and not because they've eaten.
Hair straightening iron/flat iron or curling irons - Ladies please do not use one of these in a bathroom in Brazil, nor in any other humid environment. Never under any circumstances use one while your body is wet after bathing and always wear proper footwear, not flip-flops. There have been two cases within the past month of young women killed by electric shocks while using a "chapinha" while wet and barefoot. A very high price to pay for a pretty hair style if you ask me.
Lightning storms - if possible unplug all appliances, televisions, etc. during severe lightning storms. Since most homes are only two wire construction without grounding a direct hit could cause a television or other appliance to explode causing serious injury and subtantial damage to the building itself. If possible disconnect (fixed) telephones as well and never answer a ringing (fixed) phone during a lightning storm or if you're wet from bath or pool since the ringer is 127v and could kill you.
Multiplug blocks, extension cords, etc. - avoid using plug blocks (called benjamins here) at all costs, you will end up overloading the circuits here and run the risk of setting your place on fire.
Outdoors, while in the streets especially during a rain NEVER touch metal signposts, light standards, metal fences or the like. There have been many cases of people being electrocuted because they touched something that was electrically charged, had it not been raining they might not have received a shock but since it was they became part of the circuit and were killed.
Children - be extra vigilant with small children while in Brazil. Plug outlet protectors are almost unheard of here and children can be extremely curious. Watch them closely so they don't poke sharp objects into plug outlets and get an electric shock as a result.